(1) Ferrocenyl chiral bisphosphorus ligands for highly enantioselective asymmetric hydrogenation via noncovalent ion pair interaction, C. Chen, H. Wang, Z. Zhang, S. Jin, S. Wen, J. Ji, L. W. Chung, X. Dong,* X. Zhang,* Chem. Sci. 2016, 7, 6669-6673. (Highlighted in Synfacts 2016, 12, 931).

(2) Rhodium/Yanphos-Catalyzed Asymmetric Interrupted Intramolecular Hydroaminomethylation of trans-1,2-Disubstituted Alkenes, C. Chen, S. Jin, Z. Zhang, B. Wei, H. Wang, K. Zhang, H. Lv,* X. Dong,* X. Zhang,* J. Am. Chem. Soc. 2016, 138, 9017-9020. (Spotlights in J. Am. Chem. Soc.)

(3) N-Heterocyclic Carbene Catalyzed r-Dihalomethylenation of Enals by Single-Electron Transfer, W. Yang, W. Hu, X. Dong, X. Li, J. Sun,* Angew. Chem. Int. Ed. 2016, 55, 15783-15786.

(4) Rhodium/bisphosphine-thiourea-catalyzed enantioselective hydrogenation of α,β-unsaturated N-acylpyrazoles, P. Li, X. Hu,* X. Dong,* X. Zhang,* Chem. Commun. 2016, 52, 11677-11680. (Highlighted in Synfacts 2016, 12, 1169).

(5) Synthesis of Chiral β‑Amino Nitroalkanes via Rhodium-Catalyzed Asymmetric Hydrogenation, P. Li, M. Zhou, Q. Zhao, W. Wu, X. Hu,* X. Dong,* X. Zhang,* Org. Lett. 2016, 18, 40-43. (Highlighted in Synfacts 2016, 12, 378).

(6) Iridium Catalysts with f‑Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones, W. Wu, S. Liu, M. Duan, X. Tan, C. Chen, Y. Xie, Y. Lan,* X. Dong,* X. Zhang,* Org. Lett. 2016, 18, 2938-2941. (Highlighted in Synfacts 2016, 12, 938).

(7) Selective Rhodium-Catalyzed Hydroformylation of Alkynes to α,β-Unsaturated Aldehydes with a Tetraphosphoramidite Ligand, Z. Zhang, Q. Wang, C. Chen, Z. Han, X. Dong,* X. Zhang,* Org. Lett. 2016, 18, 3290-3293. (Highlighted in Synfacts 2016, 12, 930).

(8) Highly Enantioselective Synthesis of Chiral Succinimides via Rh/Bisphosphine-Thioureα-Catalyzed Asymmetric Hydrogenation, Z. Han, P. Li, Z. Zhang, C. Chen, Q. Wang, X. Dong,* X. Zhang,* ACS Catal. 2016, 6, 6214-6218. (Highlighted in Synfacts 2008, 988).

(9) Readily Accessible and Highly Efficient Ferrocene-Based Amino-Phosphine-Alcohol (f-Amphol) Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of Simple Ketones, J. Yu, M. Duan, W. Wu, X. Qi, P. Xue, Y. Lan,* X. Dong,* X. Zhang,* Chem. Eur. J. 2016, DOI: 10.1002/chem.201604855.

(10) Recent progress in rhodium-catalyzed Hydroaminomethylation, C. Chen, X. Dong,* X. Zhang,* Org. Chem. Front. 2016, 3, 1359-1370.

(11) Rhodium-catalyzed asymmetric hydrogenation of unprotected β-enamine phosphonates, M. Zhou, Z. Xue, M. Cao, X. Dong,* X. Zhang*, Org. Biomol. Chem. 2016, 14, 4582-4584. (Highlighted in Synfacts 2016, 12, 722).

(12) New tetraphosphite ligands for regioselective linear hydroformylation of terminal and internal olefins, Z. Zhang, C. Chen, Q. Wang, Z. Han, X. Dong,* X. Zhang*, RSC Adv. 2016, 6, 14559-14562.

(13) Chiral Ligands for Rhodium-Catalyzed Asymmetric Hydroformylation: A Personal Account, C. Chen, X. Dong,* X. Zhang*, Chem. Rec. 2016, 16(6), 2670-2682.

(14) New synthetic strategy for chiral 2-oxazolidinones derivatives via rhodium-catalyzed asymmetric hydrogenation, Q. Wang, X. Tan, Z. Zhu, X. Dong,* X Zhang,* Tetrahedron Letters, 2016, 57, 658-662.

(15) Recent Advances in Dynamic Kinetic Resolution by Chiral Bifunctional (Thio)urea- and Squaramide-Based Organocatalysts, P. Li, X. Hu,* X. Dong,* X. Zhang,* Molecules 2016, 21, 1327-1341.

(16) Metalorganocatalysis: cooperating transitionmetal catalysis and organocatalysis through a covalent bond, X. Dong,* Q. Zhao, P. Li, C. Chen X. Zhang,* Org. Chem. Front. 2015, 2, 1425-1431.

(17) N-Heterocyclic Carbene Catalyzed Enantioselective α-Fluorination of Aliphatic Aldehydes and α-Chloro Aldehydes: Synthesis of α-Fluoro Esters, Amides, and Thioesters, X. Dong, W. Yang, W. Hu, J. Sun,* Angew. Chem., Int. Ed. 2015, 54, 660-663.

(18) Catalytic Asymmetric α-Aldol Reaction of Vinylogous N-Heterocyclic Carbene Enolates: Formation of Quaternary and Labile Tertiary Stereocenters,  X. Dong, J. Sun,* Org. Lett., 2014, 16, 2450-2453.

(19) N-Heterocyclic Carbene (NHC) Catalyzed Synthesis of α,α-Difluoro Esters, X. Dong, Y. Zhao, J. Sun,* Synlett. 2013, 24, 1221-1224.

(20) Organocatalytic asymmetric domino sulfa-Michael-aldol reactions of 2-mercaptobenzaldehyde with α,β-unsaturated N-acylpyrazoles for the construction of thiochromane, X. Dong,# X. Fang,# H.-Y. Tao, X. Zhou, C.-J. Wang,* Chem. Commun. 2012, 48, 7238-7240.

(21) Highly Efficient Catalytic Asymmetric Sulfa-Michael Addition of Thiols to trans-4,4,4-Trifluorocrotonoylpyrazole, X. Dong, X. Fang, H.-Y. Tao, X. Zhou, C.-J. Wang,* Adv. Synth. Catal. 2012, 354, 1141-1147.

(22) Organocatalytic Asymmetric Sulfa-Michael Addition of Thiols to 4,4,4-Trifluorocrotonates, X. Dong, X. Fang, C.-J. Wang,* Org. Lett. 2011, 13, 4426-4429.

(23) Organocatalytic asymmetric Michael addition of α-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters, X. Dong, H.-L. Teng, M.-C. Tong, H. Huang, H.-Y. Tao, C.-J. Wang,* Chem. Commun. 2010, 46, 6840-6842.

(24) Highly Enantioselective Direct Michael Addition of Nitrolalkanes to Nitroalkenes Catalyzed by Bifunctional Thiourea Bearing Multiple Hydrogen Bonding Donors, X. Dong, H.-L. Teng, C.-J. Wang,* Org. Lett. 2009, 11, 1265-1268.

(25) Highly anti-Selective Asymmetric Nitro-Mannich Reactions Catalyzed by Bifunctional Amine-thiourea Bearing Multiple Hydrogen Bonding Donors. C.-J. Wang,* X. Dong, Z.-H. Zhang, Z.-Y. Xue, H.-L. Teng, J. Am. Chem. Soc. 2008, 130, 8606-8607. (Highlighted in Synfacts 2008, 988).